Publications

Click on the TOC to be taken to the article!

(79) “Variable Peripheral Ligand Donation Tunes Electronic Structure and NIR II Emission in Tetrathiafulvalene Tetrathiolate Diradicaloids” McNamara, L. E.; Boyn, J-N.; Anferov, S. W.; Filatov, A. S.; Maloney, M.; Mazziotti, D. A.; Schaller, R. D.; Anderson, J. S. Submitted.

(78) “Catalytic, Spectroscopic, and Theoretical studies of Fe4S4-based Coordination Polymers as Heterogenous CPET Mediators for Electrocatalysis” Jiang, N., Darù, A., Kunstelj, Š., Vitillo, J., Czaikowski, M., Wuttig, A., Gagliardi, L., Anderson, J. S. Submitted.

(77) “Redox Chemistry Mediated Control of Morphology and Properties in Electrically Conductive Coordination Polymers: Opportunities and Challenges” Wang, L.; Anderson, J. S. Accepted.

(76) “Aliovalent Substitution Tunes Physical Properties in a Conductive Bis(dithiolene) Two-Dimensional Metal−Organic Framework” Wang, L.; Darù, A.; Jangid, B.; Chen, J-H.; Jiang, N.; Patel, S. N.; Gagliardi, L.; Anderson, J. S. Accepted.

(75) “Elucidating Nonradiative Decay in Deep Near-Infrared
Lumiphores: Leveraging New Design Principles to Develop a
Telecom Band Organic Dye Laser” McNamara, L. E.; Melnychuk, C.; Boyn, J-N.; Anferov, S. W.; Mazziotti, D. A.; Schaller, R. D.*; Anderson, J. S.* Accepted.

(74) “Selective Cobalt Mediated Formation of Hydrogen Peroxide from Water Under Mild Conditions Via Ligand Redox Non-Innocence” Anferov, S. W.; Boyn, J-N.; Mazziotti, D. A.; Anderson, J. S. J. Am. Chem. Soc., 2024, 146, 9, 5855–5863.

(73) “Metal-Ligand Cooperativity in Chemical Electrosynthesis” Czaikowski, M. E.;* Anferov, S. W.;* Anderson, J. S. Chem. Catalysis, 2024, 100922, 2667-1093.

*Indicates equal contributions to this work

(72) “Electrocatalytic Semi-Hydrogenation of Terminal Alkynes using Ligand-Based Transfer of Protons and Electrons” Czaikowski, M. E.; Anferov, S. W.; Tascher, A. P.; Anderson, J. S. J. Am. Chem. Soc. 2024, 146, 1, 476–486.

(71) “Combining Donor Strength and Oxidative Stability in Scorpionates: A Strongly Donating Fluorinated Mesoionic Tris(imidazol-5-ylidene)borate Ligand” *Scott, J. S.; *Schneider, J. G.; Tewelde, J. E.; Gardner, E. G.; Anferov, S. W.; Filatov, A. S.; Anderson, J. S. Inorg. Chem. 202362, 51, 21224–21232.

*Indicates equal contributions to this work

(70) “Origin of Weak Magnetic Coupling in a Dimanganese(II) Complex Bridged by the Tetrathiafulvalene-Tetrathiolate Radical” Lien, C-Y; Boyn, J-N.; Anferov, S. W.; Mazziotti, D. A.; Anderson, J. S.  Inorg. Chem. 2023, 62, 48, 19488–19497

(69) “Realizing Solution-Phase Room Temperature Quantum Coherence in a Tetrathiafulvalene-Based Diradicaloid Complex” McNamara, L. E.;* Zhou, A.;* Rajh, T.; Sun, L.; Anderson, J. S. Cell Rep. Phys. Sci., 2023, 4, 101693.

*Indicates equal contributions to this work

(68) “Cluster-Spin-Glass Magnetic Behavior and Morphology in the Coordination Polymer Alloys FeyCo1-yBTT” Ritchhart, A.; Chen, Z.; Behera, A.; Jeon, l-R.; Chapman, K. W.; Vaikuntanathan, S-r.; Anderson, J. S. 2023, 145, 44, 24089–24097.

 

(67) “Reconciling Imbalanced and Nonadiabatic Reactivity in Transition Metal–Oxo-Mediated Concerted Proton Electron Transfer (CPET)” Schneider, J. E.; Anderson, J. S. J. Phys. Chem. Lett. 202314, 43, 9548-9555.

(66) “Understanding Antiferromagnetic and Ligand Field Effects on Spin Crossover in a Triple-Decker Dimeric Cr(II) Complex” Sarkar, A.; Hermes, M. R.; Cramer, C. J.; Anderson, J. S.; Gagliardi, L. J. Am. Chem. Soc. 2023, 145, 41, 22394–22402.

(65) “Electrochemical Reduction of N2O with a Molecular Copper Catalyst” Martinez, J. L.; Schneider, J. E.; Anferov, S. W.; Anderson, J. S. ACS Catal., 2023, 13, 19, 12673–12680.

(64) “Tetrathiafulvalene-2,3,6,7-tetrathiolate Linker Redox-State Elucidation via S K-edge X-ray Absorption Spectroscopy” Jiang, N.; Boyn, J-N.; Ramanathan, A.; La Pierre, H. S.; Anderson, J. S. Chem. Commun., 2023, 59, 9537-9540.

 

(63) “Variable Temperature Kinetic Isotope Effects Demonstrate Extensive Tunnelling in the C-H Activation Reactivity of a Transition Metal-Oxo Complex” Schneider, J. E.; Goetz, M. K.; Anderson, J. S. Chem. Commun. 2023, 59, 8584-8587.

(62) “Potential for exciton condensation in a highly conductive amorphous polymer” Schouten, A. O.; Klevens, J. E.; Sager-Smith, L. M.; Xie, J.; Anderson, J. S.; Mazziotti, D. A. Phys. Rev. Materials, 2023, 7, 045001.

(61) “Broad Electronic Modulation of 2D Metal-Organic Frameworks Over Four Distinct Redox States” Wang, L.; Sarkar, A.; Grocke, G. L.; Laorenza, D. W.; Cheng, B.; Ritchhart, A.; Filatov, A. S.; Patel, S. N.; Gagliardi, L.; Anderson, J.S. J. Am. Chem. Soc. 2023, 145, 15, 8486–8497.

(60) “Testing the Limits of Imbalanced CPET Reactivity: Mechanistic Crossover in H-atom Abstraction by Co(III)-oxo Complexes” Zhao, N.; Goetz, M. K.; Schneider, J. E.; Anderson, J. S. J. Am. Chem. Soc. 2023, 145, 10, 5664–5673.

(59) “The Structure and Magnetic Properties of a New Family of Pseudo-1D Chromium Thiolate Coordination Polymers” Ritchhart, A.; Filatov, A. S.; Jeon, I-R.; Anderson, J. S. Inorg. Chem. 2023, 62, 6, 2817–2825.

(58) “Electrocatalytic C–H activation and fluorination using high-valent Cu” Czaikowski, M. E.; Anderson, J. S. Chem. Catalysis 2023, 3, 1, 100495.

 

(57) “Heteroatom Substitution for the Development of Near-Infrared Lumiphores” Dado, R. S.*; McNamara, L. E.*; Powers-Nash, M.*; Anderson, J. S. Tre. Chem. 2023, 5, 581-583.

*Indicates equal contributions to this work

(56) “Pre-Synthetic Redox Gated Metal-to-Insulator Transition and Photothermoelec-tric Properties in Nickel Tetrathiafulvalene-Tetrathiolate Coordination Polymers” *Xie, J.; *Pan, J.-A.; Cheng, B.; Ma, T.; Filatov, A. S.; Patel, S. N.; Park, J.; Talapin, D. V.; Anderson, J. S. J. Am. Chem. Soc. 2022, 144, 41, 19026-19037.

*Indicates equal contributions to this work

(55) “Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron-Semiquinoid Coordination Polymers” Wang, L.; Papoular, R. J.; Horwitz, N. E.; Xie, J.; Sarkar, A.; Campisi, D.; Zhao, N.; Cheng, B.; Grocke, G. L.; Ma, T.; Filatov, A. S.; Gagliardi, L.; Anderson, J. S. Angew. Chem. Int. Ed. 2022, 61, e20220784.

(54) “An Intrinsically Glassy Metallic Coordination Polymer Showing Thermally and Aerobically Robust Conductivity” Xie, J.; Ewing, S.; Boyn, J-N.; Cheng, B.; Filatov, A. S.; Ma, T.; Zhao, N.; Itani, R.; Sun, X.; Cho, H.; Patel, S. N.; Talapin, D. V.; Park, J.; Mazziotti, D. A.; Anderson, J. S. Nature 2022, 1-6.

(53) “Bright, Modular, and Switchable Near-Infrared II Emission from Compact Tetrathiafulvalene-Based Diradicaloid Complexes” McNamara, L. E.; Boyn, J-N.; Melnychuk, C.; Anferov, S. W.; Mazziotti, D. A.; Schaller, R. D.; Anderson, J. S. J. Am. Chem. Soc. 2022, 144, 36, 16447–16455

(52) “A Cobalt Adduct of an N-hydroxy-piperidinium Cation” Anferov, S. W.; Anderson, J. S. J. Coord. Chem. 2022, 75, 11-14, 1853-1864. 

(51) “Generation and Aerobic Oxidative Catalysis of a Cu(II) Superoxo Complex Supported by a Redox-Active Ligand” Czaikowski, M. E.; McNeece, A. J.; Boyn, J-N.; Jesse, K. A.; Anferov, S. W.; Filatov, A. S.; Mazziotti, D. A.; Anderson, J. S. J. Am. Chem. Soc. 2022, 144, 34, 15569–15580

(50) “Cobalt-Catalyzed Hydrogenation Reactions Enabled by Ligand-Based Storage of Dihydrogen” Anferov, S. W.; Filatov, A. S.; Anderson, J. S. ACS Catal. 2022, 12, 16, 9933–9943.

(49) “Donor-Acceptor Conjugated Copolymers Containing Transition-Metal Complex: Intrachain Magnetic Exchange Interactions and Magneto-Optical Activity” *Liu, X.; *Xie, J.; Niklas, J.; Turner, E. E.; Yuan, D.; Anderson, J. S.; Rack, J. J.; Poluektov, O. G.; Yu, L. Chem. Mater. 2022, 34, 5740-5747.

*Indicates equal contributions to this work

(48) “Interplay of Electronic and Geometric Structure Tunes Organic Biradical Character in Bimetallic Tetrathiafulvalene Tetrathiolate Complexes” Boyn, J-N.; McNamara, L. E.; Anderson, J. S.; Mazziotti, D. A. J. Phys. Chem. A. 2022, 126, 3329-3337.

(47) “Electrostatic vs. Inductive Effects in Phosphine Ligand Donor Properties and Reactivity” Kelty, M. L.; McNeece, A. J.; Filatov, A. S.; Anderson, J. S. Chem. Sci. 2022, 13, 4377-4387.

 

(46) “Metal-Ligand Cooperative Transfer of Protons and Electrons” *Anferov, S. W.; *Czaikowski, M. E.; Anderson, J. S. Tre. Chem. 20213, 993-996.

*Indicates equal contributions to this work

(45) “Enzyme-Like Hydroxylation of Aliphatic C–H Bonds From an Isolable Co-Oxo Complex” Goetz, M. K.; Schneider, J. E.; Filatov, A. S.; Jesse, K. A.; Anderson, J. S. J. Am. Chem. Soc. 2021, 143, 20849-20862.

(44) “Direct Aerobic Generation of a Ferric Hydroperoxo Intermediate via a Preorganized Secondary Coordination Sphere” Jesse, K. A.; Anferov, S. W.; Collins, K. A.; Valdez-Moriera, J. A.; Czaikowski, M. E.; Filatov, A. S.; Anderson, J. S. J. Am. Chem. Soc. 2021143, 18121-18130.

(43) “Steric and Electronic Effects of Ligand Substitution on Redox-Active Fe4S4-Based Coordination Polymers” *Salinas, O.; *Xie, J.; Papoular, R. J.; Horwitz, N. E.; Elkaim, E.; Filatov, A. S. Anderson, J. S. Dalton Trans.2021, 50, 10798-10805.

*Indicates equal contributions to this work

(42) “Two, three, or not to be? Elucidating Multiple Bonding in d6 Pseudotetrahedral Oxo and Imide Complexes” *Gardner, J. G.; *Schneider, J. E.; Anderson, J. S. Inorg. Chem. 2021, 60, 13854-13860.

*Indicates equal contributions to this work

(41) “Iron(II) Complexes Featuring a Redox-Active Dihydrazonopyrrole Ligand” Jesse, K. A.; Chang, M.-C.; Filatov, A. S.; Anderson, J. S. Z. anorg. allg. Chem. 2021, 647, 1415-1420.

(40) “Catalytic Hydrogenation Enabled by Ligand-Based Storage of Hydrogen” *McNeece, A. J.; *Jesse, K. A.;  Filatov, A. S.; Schneider, J. E.; Anderson, J. S. Chem. Commun. 2021, 57, 3869-3872.

*Indicates equal contributions to this work

(39) “Statistical Analysis of C-H Activation by Transition Metal Oxo Species Supports Thermodynamic Control Over Reactivity” Schneider, J. E.; Goetz, M. K.; Anderson, J. S.  Chem. Sci. 202112, 4173-4183.

(38) Goetz, M. K.; Anderson, J. S. “Cobalt-Oxo Complexes” In Comprehensive Coordination Chemistry 3 (Lu, Y.; Que, L.,Eds.) 2021 Vol. 8; Elsevier: Oxford. 

(37) “Magnetically Coupled Iron Azide Chains” Lugosan, A.; Kawamura, A.; Dickie, D. A.; Zeller, M.; Anderson, J. S.; Lee, W-T. Inorganica Chim. Acta2021516, 120150.

(36) “Generation and Reactivity of a Ni(III)2(m-1,2-peroxo) Complex ” Zhao, N.; Filatov, A. S.; Xie, J.; Hill, E. A.; Rogachev, A. Y.; Anderson, J. S. J. Am. Chem. Soc.2020, 142, 21634-21639.

(35) “Direct Optical Patterning of Quantum Dot Light-Emitting Diodes via In Situ Ligand Exchange” Cho, H.; Pan, J-A.; Wu, H.; Lan, X.; Coropceanu, I.; Wang, Y.; Cho, W.; Hill, E. A.; Anderson, J. S.; Talapin, D. V. Adv. Mater.202032, 2003805.

(34) “The Electronic Structure of a B-diketiminate Manganese Hydride Dimer” Oh, C.; Siewe, J.; Nguyen, T. T.; Kawamura, A.; Flores, M.; Groy, T. L.; Anderson, J. S.; Trovitch, R. J.; Baik, M-H. Dalton Trans.202049, 14463-14474.

(33) “Reversible Switching of Organic Diradical Character via Iron-Based Spin-Crossover” *Kawamura, A.; *Xie, J.; Boyn, J-N.; Jesse, K. A.; McNeece, A. J.; Hill, E. A.; Collins, K. A.; Valdez-Moreira, J. A.; Filatov, A. S.; Kurutz, J. W.; Mazziotti, D. A.; Anderson, J. S. J. Am. Chem. Soc. 2020142, 17670-17680.

*Indicates equal contributions to this work

(32) “Heavy Chalcogenide-Transition Metal Clusters as Coordination Polymer Nodes” *Xie, J.; *Wang, L.; Anderson, J. S. Chem. Sci. 2020, 11, 8350-8372.

*Indicates equal contributions to this work

(31) “Entangled Electrons Drive a non Superexchange Mechanism in a Cobalt Quinoid Dimer Complex” Boyn, J-N.; Xie, J.; Anderson, J. S.; Mazziotti, D. A. J. Phys. Chem. Lett. 2020, 11, 4584-4590.

(30) “Generation and Oxidative Reactivity of a Ni(II) Superoxo Complex via Ligand-Based Redox Non-Innocence” McNeece, A. J.; Jesse, K. A.; Xie, J.; Filatov, A. S.; Anderson, J. S. J. Am. Chem. Soc. 2020, 142, 10824-10832.

(29) “Nickel(II)-Methyl Complexes Adopting Idealized Seesaw Geometries” *Hill, E.A.; *Zhao, N.; Filatov, A. S.; Anderson, J. S. Chem. Commun2020, 56, 7861-7864.

*Indicates equal contributions to this work

(28) “Synthesis, Modular Composition, and Electrochemical Properties of Lamellar Iron Sulfides” Horwitz, N. E.; Shevchenko, E. V.; Park, J.; Lee, E.; Xie, J.; Filatov, A. S.; Anderson, J. S. J. Mat. Chem. A 2020, 8, 15834-15844.

(27) “Redox, Transmetalation, and Stacking Properties of Tetrathiafulvalene-2,3,6,7-tetrathiolate Bridged Tin and Nickel Compounds” Xie, J.; Boyn, J-N.; Filatov, A. S.; McNeece, A. J.; Mazziotti, D. A.; Anderson, J. S. Chem. Sci. 202011, 1066-1078.

(26) “Nickel-Mediated Dehydrogenative Aryl-Aryl Homocoupling of a Bulky Phosphino-Pyridine” Mannava, V.; Jesse, K. A.; Anderson, J. S. Organometallics 2019, 38, 4554-4559.

(25) “Sulfonate-Ligated Coordination Polymers Incorporating Paramagnetic Transition Metals” Kawamura, A.; Filatov, A. S.; Anderson, J. S. Eur. J. Inorg. Chem. 201921, 2613-2617.

(24) “Neocuproine as a Redox-Active Ligand Platform on Iron and Cobalt” Jesse, K. A.; Filatov, A. S.; Xie, J.; Anderson, J. S. Inorg. Chem. 201958, 9057-9066.

(23) “Experimental Evidence for pKa-Driven Asynchronicity in C-H Activation by a Terminal Co(III)-Oxo Complex” Goetz, M. K.; Anderson, J. S. J. Am. Chem. Soc. 2019141, 4051-4062.

(22) “Slow Magnetic Relaxation of Co(II) Single-Chains Embedded within Metal-Organic Superstructures” Kawamura, A.; Filatov, A. S.; Anderson, J. S.; Jeon, I-R. Inorg. Chem. 201958, 3764-3773.

(21) “Redox-Active 1D Coordination Polymers of Iron-Sulfur Clusters” *Horwitz, N. E.; *Xie, J.; Filatov, A. S.; Papoular, R. J.; Shepard, W. E.; Grahn, M. P.; Gilder, C.; Anderson, J. S. J. Am. Chem. Soc. 2019141, 3940-3951.

*Indicates equal contributions to this work

(20) “Imidazole for Pyridine Substitution Leads to Enhanced Activity Under Milder Conditions in Co Water Oxidation Electrocatalysis” *McMillion, N. D.; *Wilson, A. W.; Goetz, M. K.; Chang, M-C.; Lin, C-C.; Feng, W-J.; McCrory, C. C.; Anderson, J. S. Inorg. Chem. 201958, 1391-1397.

*Indicates equal contributions to this work

(19) “Reversible Homolytic Activation of Water via Metal-Ligand Cooperativity in a T-shaped Ni(II) Complex” Chang, M-C; Jesse, K. A.; Filatov, A. S.; Anderson, J. S. Chem. Sci. 201910, 1360-1367.

(18) “Isolation of a Terminal Co(III)-Oxo Complex” Goetz, M. K.; Hill, E. A.; Filatov, A. S.; Anderson, J. S. J. Am. Chem. Soc., 2018140, 13176-13180.

Selected JACS Spotlight: 
https://pubs.acs.org/doi/10.1021/jacs.8b10882

Selected for Cover Art: Volume 140, Issue 41

(17) “Redox-Activity, Ligand Protonation, and Variable Coordination Modes of Diimino-Pyrrole Complexes of Palladium” McNeece, A. J.; Chang, M-C.; Filatov, A. S.; Anderson, J. S. Inorg. Chem., 201857, 7044-7050.

(16) “Monodisperse InAs Quantum Dots from Aminoarsine Precursors: Understanding the Role of Reducing Agent” Srivastava, V.; Dunietz, E.; Kamysbayev, V.; Anderson, J. S.; Talapin, D. V. Chem. Mater., 201830, 3623-3627.

(15) “Isolable Iodosylarene and Iodoxyarene Adducts of Co and Their O-atom Transfer and C-H Activation Reactivity” Hill, E. A.; Kelty, M. L.; Filatov, A. S.; Anderson, J. S. Chem. Sci.20189, 4493-4499.

(14) “Ligand-Based Storage of Protons and Electrons in Dihydrozonopyrrole Complexes of Nickel” Chang, M-C.; McNeece, A. J.; Hill, E. A.; Filatov, A. S.; Anderson, J. S. Chem. Eur. J.201824, 8001-8008.

(13) “Incorporation of Pyrazine and Bipyridine Linkers with High-Spin Fe(II) and Co(II) in a Metal-Organic Framework” Kawamura, A.; Greenwood, A. R.; Filatov, A. S.; Gallagher, A. T.; Galli, G.; Anderson J. S. Inorg. Chem. 201756, 3349-3356.

Publications Prior to UChicago

(12) “A Structurally-Characterized Peroxomanganese(IV) Porphyrin from Reversible O2 Binding within a Metal-Organic Framework” Gallagher, A. T.; Lee, J. Y.; Kathiresan, V.; Anderson, J. S.; Hoffman, B. M.; Harris, T. D. Chem. Sci.20189, 1596-1603.

(11) “High-Throughput Synthesis and Characterization of Nanocrystalline Porphyrinic Zirconium Metal-Organic Frameworks” *Kelty, M. L.; *Morris, W.; Gallagher, A. T.; Anderson, J. S.; Brown, K. A.; Mirkin, C. A.; Harris, T. D. Chem. Comm. 201652, 7854-7857.

*Indicates equal contributions to this work

(10) “Dioxygen Binding at a Four-Coordinate Cobaltous Porphyrin Site in a Metal-Organic Framework: Structural, EPR, and O2 Adsorption Analysis” *Gallagher, A. T.; *Kelty, M. L.; Park, J. G.; Anderson, J. S.; Mason, J. A.; Walsh, J. P. S.; Collins, S. L.; Harris, T. D. Inorg. Chem. Front. 2016, 3, 536-540.

*Indicates equal contributions to this work

(9) “Electron Hopping through Double-Exchange Coupling in a Mixed-Valence Diiminobenzoquinone-Bridged Fe2 Complex” Gaudette, A. I.; Jeon, I.-R.; Anderson, J. S.; Harris, T. D. J. Am. Chem. Soc. 2015137, 12617-12626.

(8) “Characterization of an Fe≡N–NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3″ Anderson, J. S.; Cutsail, G. E.; Rittle, J.; Connor, B. A.; Gunderson, W. A.; Zhang, L.; Hoffman, B. M.; Peters, J. C. J. Am. Chem. Soc. 2015137, 7803-7809.

(7) “A Five-Coordinate Heme Dioxygen Adduct Isolated within a Metal-Organic Framework” Anderson, J. S.; Gallagher, A. T.; Mason, J. A.; Harris, T. D. J. Am. Chem. Soc. 2014136, 16489-16492.

(6) “Influence of Electronic Spin and Spin-Orbit Coupling on Decoherence in Mononuclear Transition Metal Complexes.” Graham, M. J.; Zadrozny, J. M.; Shiddiq, M.; Anderson, J. S.; Fataftah, M. S.; Hill, S.; Freedman, D. E. J. Am. Chem. Soc. 2014, 136, 7623-7626.

(5) “Low-Spin Pseudotetrahedral Iron(I) Sites in Fe2(μ-S) Complexes.” Anderson, J. S.; Peters, J. C. Angew. Chem. Int. Ed. 201453, 5978-5981.

(4) “Catalytic Conversion of Nitrogen to Ammonia by an Iron Model Complex.” Anderson, J. S.; Rittle, J.; Peters, J. C. Nature 2013501, 84-87.

(3) “Conversion of Fe-NH2 to Fe-N2 with release of NH3.” Anderson, J. S.; Moret, M.-E.; Peters, J. C. J. Am. Chem. Soc. 2013135, 534-537.

(2) “Synthesis and Characterization of Three-Coordinate Ni(III)-Imide Complexes.” Iluc, V. M.; Miller, A. J. M.; Anderson, J. S.; Monreal, M. J.; Mehn, M. P.; Hillhouse, G. L. J. Am. Chem. Soc. 2011133, 13055-13063.

(1) “Reactions of CO2 and CS2 with 1,2-bis(di-tert-butylphosphino)ethane Complexes of Nickel(0) and Nickel(I).” Anderson, J. S.; Iluc, V. M.; Hillhouse, G. L. Inorg. Chem201049, 10203-10207.