Publications

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(79) “Variable Peripheral Ligand Donation Tunes Electronic Structure and NIR II Emission in Tetrathiafulvalene Tetrathiolate Diradicaloids” McNamara, L. E.; Boyn, J-N.; Anferov, S. W.; Filatov, A. S.; Maloney, M.; Mazziotti, D. A.; Schaller, R. D.; Anderson, J. S. Submitted.

(78) “Catalytic, Spectroscopic, and Theoretical Studies of Fe4S4-Based Coordination Polymers as Heterogenous Coupled Proton–Electron Transfer Mediators for Electrocatalysis” Jiang, N.; Darù, A.; Kunstelj, Š.; Vitillo, J.; Czaikowski, M.; Filatov, A. S.; Wuttig, A.; Gagliardi, L.; Anderson, J. S. J. Am. Chem. Soc. 2024, Accepted.

(77) “Aliovalent Substitution Tunes Physical Properties in a Conductive Bis(dithiolene) Two-Dimensional Metal−Organic Framework” Wang, L.; Darù, A.; Jangid, B.; Chen, J-H.; Jiang, N.; Patel, S. N.; Gagliardi, L.; Anderson, J. S. J. Am. Chem. Soc. 2024, Accepted.

(76) “Redox Chemistry Mediated Control of Morphology and Properties in Electrically Conductive Coordination Polymers: Opportunities and Challenges” Wang, L.; Anderson, J. S. Chem. Mater. 2024, Accepted. 

(75) “Elucidating Nonradiative Decay in Near-Infrared
Lumiphores: Leveraging New Design Principles to Develop a Telecom Band Organic Dye Laser” McNamara, L. E.; Melnychuk, C.; Boyn, J-N.; Anferov, S. W.; Mazziotti, D. A.; Schaller, R. D.*; Anderson, J. S.* Chem 2024, Accepted.

(74) “Selective Cobalt Mediated Formation of Hydrogen Peroxide from Water Under Mild Conditions Via Ligand Redox Non-Innocence” Anferov, S. W.; Boyn, J-N.; Mazziotti, D. A.; Anderson, J. S. J. Am. Chem. Soc., 2024, 146, 9, 5855–5863.

(73) “Metal-Ligand Cooperativity in Chemical Electrosynthesis” Czaikowski, M. E.;* Anferov, S. W.;* Anderson, J. S. Chem. Catalysis, 2024, 100922, 2667-1093.

*Indicates equal contributions to this work

(72) “Electrocatalytic Semi-Hydrogenation of Terminal Alkynes using Ligand-Based Transfer of Protons and Electrons” Czaikowski, M. E.; Anferov, S. W.; Tascher, A. P.; Anderson, J. S. J. Am. Chem. Soc. 2024, 146, 1, 476–486.

(71) “Combining Donor Strength and Oxidative Stability in Scorpionates: A Strongly Donating Fluorinated Mesoionic Tris(imidazol-5-ylidene)borate Ligand” *Scott, J. S.; *Schneider, J. G.; Tewelde, J. E.; Gardner, E. G.; Anferov, S. W.; Filatov, A. S.; Anderson, J. S. Inorg. Chem. 202362, 51, 21224–21232.

*Indicates equal contributions to this work

(70) “Origin of Weak Magnetic Coupling in a Dimanganese(II) Complex Bridged by the Tetrathiafulvalene-Tetrathiolate Radical” Lien, C-Y; Boyn, J-N.; Anferov, S. W.; Mazziotti, D. A.; Anderson, J. S.  Inorg. Chem. 2023, 62, 48, 19488–19497

(69) “Realizing Solution-Phase Room Temperature Quantum Coherence in a Tetrathiafulvalene-Based Diradicaloid Complex” McNamara, L. E.;* Zhou, A.;* Rajh, T.; Sun, L.; Anderson, J. S. Cell Rep. Phys. Sci., 2023, 4, 101693.

*Indicates equal contributions to this work

(68) “Cluster-Spin-Glass Magnetic Behavior and Morphology in the Coordination Polymer Alloys FeyCo1-yBTT” Ritchhart, A.; Chen, Z.; Behera, A.; Jeon, l-R.; Chapman, K. W.; Vaikuntanathan, S-r.; Anderson, J. S. 2023, 145, 44, 24089–24097.

 

(67) “Reconciling Imbalanced and Nonadiabatic Reactivity in Transition Metal–Oxo-Mediated Concerted Proton Electron Transfer (CPET)” Schneider, J. E.; Anderson, J. S. J. Phys. Chem. Lett. 202314, 43, 9548-9555.

(66) “Understanding Antiferromagnetic and Ligand Field Effects on Spin Crossover in a Triple-Decker Dimeric Cr(II) Complex” Sarkar, A.; Hermes, M. R.; Cramer, C. J.; Anderson, J. S.; Gagliardi, L. J. Am. Chem. Soc. 2023, 145, 41, 22394–22402.

(65) “Electrochemical Reduction of N2O with a Molecular Copper Catalyst” Martinez, J. L.; Schneider, J. E.; Anferov, S. W.; Anderson, J. S. ACS Catal., 2023, 13, 19, 12673–12680.

(64) “Tetrathiafulvalene-2,3,6,7-tetrathiolate Linker Redox-State Elucidation via S K-edge X-ray Absorption Spectroscopy” Jiang, N.; Boyn, J-N.; Ramanathan, A.; La Pierre, H. S.; Anderson, J. S. Chem. Commun., 2023, 59, 9537-9540.

 

(63) “Variable Temperature Kinetic Isotope Effects Demonstrate Extensive Tunnelling in the C-H Activation Reactivity of a Transition Metal-Oxo Complex” Schneider, J. E.; Goetz, M. K.; Anderson, J. S. Chem. Commun. 2023, 59, 8584-8587.

(62) “Potential for exciton condensation in a highly conductive amorphous polymer” Schouten, A. O.; Klevens, J. E.; Sager-Smith, L. M.; Xie, J.; Anderson, J. S.; Mazziotti, D. A. Phys. Rev. Materials, 2023, 7, 045001.

(61) “Broad Electronic Modulation of 2D Metal-Organic Frameworks Over Four Distinct Redox States” Wang, L.; Sarkar, A.; Grocke, G. L.; Laorenza, D. W.; Cheng, B.; Ritchhart, A.; Filatov, A. S.; Patel, S. N.; Gagliardi, L.; Anderson, J.S. J. Am. Chem. Soc. 2023, 145, 15, 8486–8497.

(60) “Testing the Limits of Imbalanced CPET Reactivity: Mechanistic Crossover in H-atom Abstraction by Co(III)-oxo Complexes” Zhao, N.; Goetz, M. K.; Schneider, J. E.; Anderson, J. S. J. Am. Chem. Soc. 2023, 145, 10, 5664–5673.

(59) “The Structure and Magnetic Properties of a New Family of Pseudo-1D Chromium Thiolate Coordination Polymers” Ritchhart, A.; Filatov, A. S.; Jeon, I-R.; Anderson, J. S. Inorg. Chem. 2023, 62, 6, 2817–2825.

(58) “Electrocatalytic C–H activation and fluorination using high-valent Cu” Czaikowski, M. E.; Anderson, J. S. Chem. Catalysis 2023, 3, 1, 100495.

 

(57) “Heteroatom Substitution for the Development of Near-Infrared Lumiphores” Dado, R. S.*; McNamara, L. E.*; Powers-Nash, M.*; Anderson, J. S. Tre. Chem. 2023, 5, 581-583.

*Indicates equal contributions to this work

(56) “Pre-Synthetic Redox Gated Metal-to-Insulator Transition and Photothermoelec-tric Properties in Nickel Tetrathiafulvalene-Tetrathiolate Coordination Polymers” *Xie, J.; *Pan, J.-A.; Cheng, B.; Ma, T.; Filatov, A. S.; Patel, S. N.; Park, J.; Talapin, D. V.; Anderson, J. S. J. Am. Chem. Soc. 2022, 144, 41, 19026-19037.

*Indicates equal contributions to this work

(55) “Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron-Semiquinoid Coordination Polymers” Wang, L.; Papoular, R. J.; Horwitz, N. E.; Xie, J.; Sarkar, A.; Campisi, D.; Zhao, N.; Cheng, B.; Grocke, G. L.; Ma, T.; Filatov, A. S.; Gagliardi, L.; Anderson, J. S. Angew. Chem. Int. Ed. 2022, 61, e20220784.

(54) “An Intrinsically Glassy Metallic Coordination Polymer Showing Thermally and Aerobically Robust Conductivity” Xie, J.; Ewing, S.; Boyn, J-N.; Cheng, B.; Filatov, A. S.; Ma, T.; Zhao, N.; Itani, R.; Sun, X.; Cho, H.; Patel, S. N.; Talapin, D. V.; Park, J.; Mazziotti, D. A.; Anderson, J. S. Nature 2022, 1-6.

(53) “Bright, Modular, and Switchable Near-Infrared II Emission from Compact Tetrathiafulvalene-Based Diradicaloid Complexes” McNamara, L. E.; Boyn, J-N.; Melnychuk, C.; Anferov, S. W.; Mazziotti, D. A.; Schaller, R. D.; Anderson, J. S. J. Am. Chem. Soc. 2022, 144, 36, 16447–16455

(52) “A Cobalt Adduct of an N-hydroxy-piperidinium Cation” Anferov, S. W.; Anderson, J. S. J. Coord. Chem. 2022, 75, 11-14, 1853-1864. 

(51) “Generation and Aerobic Oxidative Catalysis of a Cu(II) Superoxo Complex Supported by a Redox-Active Ligand” Czaikowski, M. E.; McNeece, A. J.; Boyn, J-N.; Jesse, K. A.; Anferov, S. W.; Filatov, A. S.; Mazziotti, D. A.; Anderson, J. S. J. Am. Chem. Soc. 2022, 144, 34, 15569–15580

(50) “Cobalt-Catalyzed Hydrogenation Reactions Enabled by Ligand-Based Storage of Dihydrogen” Anferov, S. W.; Filatov, A. S.; Anderson, J. S. ACS Catal. 2022, 12, 16, 9933–9943.

(49) “Donor-Acceptor Conjugated Copolymers Containing Transition-Metal Complex: Intrachain Magnetic Exchange Interactions and Magneto-Optical Activity” *Liu, X.; *Xie, J.; Niklas, J.; Turner, E. E.; Yuan, D.; Anderson, J. S.; Rack, J. J.; Poluektov, O. G.; Yu, L. Chem. Mater. 2022, 34, 5740-5747.

*Indicates equal contributions to this work

(48) “Interplay of Electronic and Geometric Structure Tunes Organic Biradical Character in Bimetallic Tetrathiafulvalene Tetrathiolate Complexes” Boyn, J-N.; McNamara, L. E.; Anderson, J. S.; Mazziotti, D. A. J. Phys. Chem. A. 2022, 126, 3329-3337.

(47) “Electrostatic vs. Inductive Effects in Phosphine Ligand Donor Properties and Reactivity” Kelty, M. L.; McNeece, A. J.; Filatov, A. S.; Anderson, J. S. Chem. Sci. 2022, 13, 4377-4387.

 

(46) “Metal-Ligand Cooperative Transfer of Protons and Electrons” *Anferov, S. W.; *Czaikowski, M. E.; Anderson, J. S. Tre. Chem. 20213, 993-996.

*Indicates equal contributions to this work

(45) “Enzyme-Like Hydroxylation of Aliphatic C–H Bonds From an Isolable Co-Oxo Complex” Goetz, M. K.; Schneider, J. E.; Filatov, A. S.; Jesse, K. A.; Anderson, J. S. J. Am. Chem. Soc. 2021, 143, 20849-20862.

(44) “Direct Aerobic Generation of a Ferric Hydroperoxo Intermediate via a Preorganized Secondary Coordination Sphere” Jesse, K. A.; Anferov, S. W.; Collins, K. A.; Valdez-Moriera, J. A.; Czaikowski, M. E.; Filatov, A. S.; Anderson, J. S. J. Am. Chem. Soc. 2021143, 18121-18130.

(43) “Steric and Electronic Effects of Ligand Substitution on Redox-Active Fe4S4-Based Coordination Polymers” *Salinas, O.; *Xie, J.; Papoular, R. J.; Horwitz, N. E.; Elkaim, E.; Filatov, A. S. Anderson, J. S. Dalton Trans.2021, 50, 10798-10805.

*Indicates equal contributions to this work

(42) “Two, three, or not to be? Elucidating Multiple Bonding in d6 Pseudotetrahedral Oxo and Imide Complexes” *Gardner, J. G.; *Schneider, J. E.; Anderson, J. S. Inorg. Chem. 2021, 60, 13854-13860.

*Indicates equal contributions to this work

(41) “Iron(II) Complexes Featuring a Redox-Active Dihydrazonopyrrole Ligand” Jesse, K. A.; Chang, M.-C.; Filatov, A. S.; Anderson, J. S. Z. anorg. allg. Chem. 2021, 647, 1415-1420.

(40) “Catalytic Hydrogenation Enabled by Ligand-Based Storage of Hydrogen” *McNeece, A. J.; *Jesse, K. A.;  Filatov, A. S.; Schneider, J. E.; Anderson, J. S. Chem. Commun. 2021, 57, 3869-3872.

*Indicates equal contributions to this work

(39) “Statistical Analysis of C-H Activation by Transition Metal Oxo Species Supports Thermodynamic Control Over Reactivity” Schneider, J. E.; Goetz, M. K.; Anderson, J. S.  Chem. Sci. 202112, 4173-4183.

(38) Goetz, M. K.; Anderson, J. S. “Cobalt-Oxo Complexes” In Comprehensive Coordination Chemistry 3 (Lu, Y.; Que, L.,Eds.) 2021 Vol. 8; Elsevier: Oxford. 

(37) “Magnetically Coupled Iron Azide Chains” Lugosan, A.; Kawamura, A.; Dickie, D. A.; Zeller, M.; Anderson, J. S.; Lee, W-T. Inorganica Chim. Acta2021516, 120150.

(36) “Generation and Reactivity of a Ni(III)2(m-1,2-peroxo) Complex ” Zhao, N.; Filatov, A. S.; Xie, J.; Hill, E. A.; Rogachev, A. Y.; Anderson, J. S. J. Am. Chem. Soc.2020, 142, 21634-21639.

(35) “Direct Optical Patterning of Quantum Dot Light-Emitting Diodes via In Situ Ligand Exchange” Cho, H.; Pan, J-A.; Wu, H.; Lan, X.; Coropceanu, I.; Wang, Y.; Cho, W.; Hill, E. A.; Anderson, J. S.; Talapin, D. V. Adv. Mater.202032, 2003805.

(34) “The Electronic Structure of a B-diketiminate Manganese Hydride Dimer” Oh, C.; Siewe, J.; Nguyen, T. T.; Kawamura, A.; Flores, M.; Groy, T. L.; Anderson, J. S.; Trovitch, R. J.; Baik, M-H. Dalton Trans.202049, 14463-14474.

(33) “Reversible Switching of Organic Diradical Character via Iron-Based Spin-Crossover” *Kawamura, A.; *Xie, J.; Boyn, J-N.; Jesse, K. A.; McNeece, A. J.; Hill, E. A.; Collins, K. A.; Valdez-Moreira, J. A.; Filatov, A. S.; Kurutz, J. W.; Mazziotti, D. A.; Anderson, J. S. J. Am. Chem. Soc. 2020142, 17670-17680.

*Indicates equal contributions to this work

(32) “Heavy Chalcogenide-Transition Metal Clusters as Coordination Polymer Nodes” *Xie, J.; *Wang, L.; Anderson, J. S. Chem. Sci. 2020, 11, 8350-8372.

*Indicates equal contributions to this work

(31) “Entangled Electrons Drive a non Superexchange Mechanism in a Cobalt Quinoid Dimer Complex” Boyn, J-N.; Xie, J.; Anderson, J. S.; Mazziotti, D. A. J. Phys. Chem. Lett. 2020, 11, 4584-4590.

(30) “Generation and Oxidative Reactivity of a Ni(II) Superoxo Complex via Ligand-Based Redox Non-Innocence” McNeece, A. J.; Jesse, K. A.; Xie, J.; Filatov, A. S.; Anderson, J. S. J. Am. Chem. Soc. 2020, 142, 10824-10832.

(29) “Nickel(II)-Methyl Complexes Adopting Idealized Seesaw Geometries” *Hill, E.A.; *Zhao, N.; Filatov, A. S.; Anderson, J. S. Chem. Commun2020, 56, 7861-7864.

*Indicates equal contributions to this work

(28) “Synthesis, Modular Composition, and Electrochemical Properties of Lamellar Iron Sulfides” Horwitz, N. E.; Shevchenko, E. V.; Park, J.; Lee, E.; Xie, J.; Filatov, A. S.; Anderson, J. S. J. Mat. Chem. A 2020, 8, 15834-15844.

(27) “Redox, Transmetalation, and Stacking Properties of Tetrathiafulvalene-2,3,6,7-tetrathiolate Bridged Tin and Nickel Compounds” Xie, J.; Boyn, J-N.; Filatov, A. S.; McNeece, A. J.; Mazziotti, D. A.; Anderson, J. S. Chem. Sci. 202011, 1066-1078.

(26) “Nickel-Mediated Dehydrogenative Aryl-Aryl Homocoupling of a Bulky Phosphino-Pyridine” Mannava, V.; Jesse, K. A.; Anderson, J. S. Organometallics 2019, 38, 4554-4559.

(25) “Sulfonate-Ligated Coordination Polymers Incorporating Paramagnetic Transition Metals” Kawamura, A.; Filatov, A. S.; Anderson, J. S. Eur. J. Inorg. Chem. 201921, 2613-2617.

(24) “Neocuproine as a Redox-Active Ligand Platform on Iron and Cobalt” Jesse, K. A.; Filatov, A. S.; Xie, J.; Anderson, J. S. Inorg. Chem. 201958, 9057-9066.

(23) “Experimental Evidence for pKa-Driven Asynchronicity in C-H Activation by a Terminal Co(III)-Oxo Complex” Goetz, M. K.; Anderson, J. S. J. Am. Chem. Soc. 2019141, 4051-4062.

(22) “Slow Magnetic Relaxation of Co(II) Single-Chains Embedded within Metal-Organic Superstructures” Kawamura, A.; Filatov, A. S.; Anderson, J. S.; Jeon, I-R. Inorg. Chem. 201958, 3764-3773.

(21) “Redox-Active 1D Coordination Polymers of Iron-Sulfur Clusters” *Horwitz, N. E.; *Xie, J.; Filatov, A. S.; Papoular, R. J.; Shepard, W. E.; Grahn, M. P.; Gilder, C.; Anderson, J. S. J. Am. Chem. Soc. 2019141, 3940-3951.

*Indicates equal contributions to this work

(20) “Imidazole for Pyridine Substitution Leads to Enhanced Activity Under Milder Conditions in Co Water Oxidation Electrocatalysis” *McMillion, N. D.; *Wilson, A. W.; Goetz, M. K.; Chang, M-C.; Lin, C-C.; Feng, W-J.; McCrory, C. C.; Anderson, J. S. Inorg. Chem. 201958, 1391-1397.

*Indicates equal contributions to this work

(19) “Reversible Homolytic Activation of Water via Metal-Ligand Cooperativity in a T-shaped Ni(II) Complex” Chang, M-C; Jesse, K. A.; Filatov, A. S.; Anderson, J. S. Chem. Sci. 201910, 1360-1367.

(18) “Isolation of a Terminal Co(III)-Oxo Complex” Goetz, M. K.; Hill, E. A.; Filatov, A. S.; Anderson, J. S. J. Am. Chem. Soc., 2018140, 13176-13180.

Selected JACS Spotlight: 
https://pubs.acs.org/doi/10.1021/jacs.8b10882

Selected for Cover Art: Volume 140, Issue 41

(17) “Redox-Activity, Ligand Protonation, and Variable Coordination Modes of Diimino-Pyrrole Complexes of Palladium” McNeece, A. J.; Chang, M-C.; Filatov, A. S.; Anderson, J. S. Inorg. Chem., 201857, 7044-7050.

(16) “Monodisperse InAs Quantum Dots from Aminoarsine Precursors: Understanding the Role of Reducing Agent” Srivastava, V.; Dunietz, E.; Kamysbayev, V.; Anderson, J. S.; Talapin, D. V. Chem. Mater., 201830, 3623-3627.

(15) “Isolable Iodosylarene and Iodoxyarene Adducts of Co and Their O-atom Transfer and C-H Activation Reactivity” Hill, E. A.; Kelty, M. L.; Filatov, A. S.; Anderson, J. S. Chem. Sci.20189, 4493-4499.

(14) “Ligand-Based Storage of Protons and Electrons in Dihydrozonopyrrole Complexes of Nickel” Chang, M-C.; McNeece, A. J.; Hill, E. A.; Filatov, A. S.; Anderson, J. S. Chem. Eur. J.201824, 8001-8008.

(13) “Incorporation of Pyrazine and Bipyridine Linkers with High-Spin Fe(II) and Co(II) in a Metal-Organic Framework” Kawamura, A.; Greenwood, A. R.; Filatov, A. S.; Gallagher, A. T.; Galli, G.; Anderson J. S. Inorg. Chem. 201756, 3349-3356.

Publications Prior to UChicago

(12) “A Structurally-Characterized Peroxomanganese(IV) Porphyrin from Reversible O2 Binding within a Metal-Organic Framework” Gallagher, A. T.; Lee, J. Y.; Kathiresan, V.; Anderson, J. S.; Hoffman, B. M.; Harris, T. D. Chem. Sci.20189, 1596-1603.

(11) “High-Throughput Synthesis and Characterization of Nanocrystalline Porphyrinic Zirconium Metal-Organic Frameworks” *Kelty, M. L.; *Morris, W.; Gallagher, A. T.; Anderson, J. S.; Brown, K. A.; Mirkin, C. A.; Harris, T. D. Chem. Comm. 201652, 7854-7857.

*Indicates equal contributions to this work

(10) “Dioxygen Binding at a Four-Coordinate Cobaltous Porphyrin Site in a Metal-Organic Framework: Structural, EPR, and O2 Adsorption Analysis” *Gallagher, A. T.; *Kelty, M. L.; Park, J. G.; Anderson, J. S.; Mason, J. A.; Walsh, J. P. S.; Collins, S. L.; Harris, T. D. Inorg. Chem. Front. 2016, 3, 536-540.

*Indicates equal contributions to this work

(9) “Electron Hopping through Double-Exchange Coupling in a Mixed-Valence Diiminobenzoquinone-Bridged Fe2 Complex” Gaudette, A. I.; Jeon, I.-R.; Anderson, J. S.; Harris, T. D. J. Am. Chem. Soc. 2015137, 12617-12626.

(8) “Characterization of an Fe≡N–NH2 Intermediate Relevant to Catalytic N2 Reduction to NH3″ Anderson, J. S.; Cutsail, G. E.; Rittle, J.; Connor, B. A.; Gunderson, W. A.; Zhang, L.; Hoffman, B. M.; Peters, J. C. J. Am. Chem. Soc. 2015137, 7803-7809.

(7) “A Five-Coordinate Heme Dioxygen Adduct Isolated within a Metal-Organic Framework” Anderson, J. S.; Gallagher, A. T.; Mason, J. A.; Harris, T. D. J. Am. Chem. Soc. 2014136, 16489-16492.

(6) “Influence of Electronic Spin and Spin-Orbit Coupling on Decoherence in Mononuclear Transition Metal Complexes.” Graham, M. J.; Zadrozny, J. M.; Shiddiq, M.; Anderson, J. S.; Fataftah, M. S.; Hill, S.; Freedman, D. E. J. Am. Chem. Soc. 2014, 136, 7623-7626.

(5) “Low-Spin Pseudotetrahedral Iron(I) Sites in Fe2(μ-S) Complexes.” Anderson, J. S.; Peters, J. C. Angew. Chem. Int. Ed. 201453, 5978-5981.

(4) “Catalytic Conversion of Nitrogen to Ammonia by an Iron Model Complex.” Anderson, J. S.; Rittle, J.; Peters, J. C. Nature 2013501, 84-87.

(3) “Conversion of Fe-NH2 to Fe-N2 with release of NH3.” Anderson, J. S.; Moret, M.-E.; Peters, J. C. J. Am. Chem. Soc. 2013135, 534-537.

(2) “Synthesis and Characterization of Three-Coordinate Ni(III)-Imide Complexes.” Iluc, V. M.; Miller, A. J. M.; Anderson, J. S.; Monreal, M. J.; Mehn, M. P.; Hillhouse, G. L. J. Am. Chem. Soc. 2011133, 13055-13063.

(1) “Reactions of CO2 and CS2 with 1,2-bis(di-tert-butylphosphino)ethane Complexes of Nickel(0) and Nickel(I).” Anderson, J. S.; Iluc, V. M.; Hillhouse, G. L. Inorg. Chem201049, 10203-10207.